A novel receptor based on a C3v-symmetrical PN3-calix[6]cryptand.
Identifieur interne : 001340 ( Main/Exploration ); précédent : 001339; suivant : 001341A novel receptor based on a C3v-symmetrical PN3-calix[6]cryptand.
Auteurs : Xianshun Zeng [France] ; Nicolas Hucher ; Olivia Reinaud ; Ivan JabinSource :
- The Journal of organic chemistry [ 0022-3263 ] ; 2004.
Abstract
A C3v-symmetrical PN3-calix[6]cryptand was prepared in six steps from the known 1,3,5-tris-methylated calix[6]arene through a remarkably efficient [1 + 1] macrocyclization reaction. A 1H NMR study showed that the P,N-crypto cap rigidifies the whole edifice in a cone conformation ideal for molecular recognition applications. The ability of this new receptor to perform selective endo-complexation is illustrated with ammonium guests.
DOI: 10.1021/jo048814b
PubMed: 15387616
Affiliations:
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A 1H NMR study showed that the P,N-crypto cap rigidifies the whole edifice in a cone conformation ideal for molecular recognition applications. The ability of this new receptor to perform selective endo-complexation is illustrated with ammonium guests.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Haute-Normandie</li><li>Région Normandie</li></region><settlement><li>Le Havre</li></settlement><orgName><li>Université du Havre</li></orgName></list><tree><noCountry><name sortKey="Hucher, Nicolas" sort="Hucher, Nicolas" uniqKey="Hucher N" first="Nicolas" last="Hucher">Nicolas Hucher</name><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name></noCountry><country name="France"><region name="Région Normandie"><name sortKey="Zeng, Xianshun" sort="Zeng, Xianshun" uniqKey="Zeng X" first="Xianshun" last="Zeng">Xianshun Zeng</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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